Organophosphates as a class

Class Acetylcholinesterase inhibitor
Chemistry
Organophosphate
Routes of administration

Oral, inhaled, or transdermal

Absorption
100% oral bioavailability, and generally absorbed rapidly via any route, including dermal and inhaled
Solubility
pKa values between 6 and 8; most are only soluble in organic solvents, which give them the characteristic smell.
Distribution
VOD= 1-5L/kg, but very variable. Moderate to high protein binding (30–90%),
Metabolism
Mostly metabolism by the liver; and a fair few have active metabolites.
Elimination
minimal renal elimination
Time course of action
There is a wide range of half-lives, but most a reasonably long-lived (eg. chlorpyrifos, 27 hrs).
Target receptor

Acetylcholinesterase

Mechanism of action

By binding to acetylcholinesterase, organophosphates acts as competing substrates, replacing acetylcholine and decreasing acetylcholinesterase activity. The drug is metabolised much more slowly than acetylcholine, which means the enzyme is blocked for a sustained period. The bond between the drug and the enzyme also increases with age.

Clinical effects
Literature reference

Testai et al, 2010

CICM details of understanding Level 3
Mentioned around Deranged Physiology
Related SAQs